Vapor Liquid Equilibrium of Aqueous Diethanolamine Solution for Carbon Dioxide Capture Processes
نویسندگان
چکیده
Objectives : Acid gases such as carbon dioxide (CO<sub>2</sub>) and hydrogen sulfide (H<sub>2</sub>S) that cause global warming are mainly generated in chemical processes. As a technology for reducing acid gas, the post-combustion capture process is representative. Aqueous alkanolamine solution, which used absorption process, most representative absorbent. Thermodynamic data of vapor-liquid equilibrium important economics design operation. In this study, water + DEA measured so DEA, secondary amine, can be it designing new process.Methods Vapor-liquid mixture (diethanolamine) were under isothermal conditions 393.15 K using HSGC (Headspace Gas Chromatography).Results Discussion The correlated NRTL, an activity coefficient model. addition, additional thermodynamic absorbent mixture, density aqueous was at temperature 303.15 to 333.15 meter (Anton Paar DMA4500). converted into excess volume, volume Redilchi-Kister-Muggianu equation. Using water+DEA data, expected cost operating
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ژورنال
عنوان ژورنال: Journal of Korean Society of Environmental Engineers
سال: 2023
ISSN: ['1225-5025', '2383-7810']
DOI: https://doi.org/10.4491/ksee.2023.45.2.119